Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes
We report a visible-light-induced copper-catalyzed highly enantioselective umpolung allylic acylation reaction with acylsilanes as acyl anion equivalents. Triplet-quenching experiments and DFT calculations supported our reaction design, which is…..
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Yusuke Ueda, Yusuke Masuda, Tomohiro Iwai, Keisuke Imaeda, Hiroki Takeuchi, Kosei Ueno, Min Gao, Jun-ya Hasegawa, and Masaya Sawamura
Journal of the American Chemical Society, January 6, 2022