Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes

SAWAMURA Masaya

Department of Chemistry

Jan. 14, 2022

Press release (in Japanese)

Abstract
We report a visible-light-induced copper-catalyzed highly enantioselective umpolung allylic acylation reaction with acylsilanes as acyl anion equivalents. Triplet-quenching experiments and DFT calculations supported our reaction design, which is…..

Read the original article on Journal of the American Chemical Society

Article Information:
Yusuke Ueda, Yusuke Masuda, Tomohiro Iwai, Keisuke Imaeda, Hiroki Takeuchi, Kosei Ueno, Min Gao, Jun-ya Hasegawa, and Masaya Sawamura
Journal of the American Chemical Society, January 6, 2022
DOI: 10.1021/jacs.1c11526