Convergent approach for direct cross-coupling enabled by flash irreversible generation of cationic and anionic species
カチオン及びアニオンを異なる空間で発生させ、それらの直接反応に成功。
Abstract
In biosynthesis multiple kinds of reactive intermediates are generated, transported, and reacted across different parts of organisms, enabling highly sophisticated synthetic reactions. Herein we report a convergent synthetic approach, which utilizes dual intermediates of cationic and carbanionic species in a single step, hinted at by the ideal reaction conditions. By reactions of unsaturated precursors, such as enamines, with….
Read the original article on Nature Communications
Article Information：
Soutome, H., Yamashita, H., Shimizu, Y. et al.
Convergent approach for direct cross-coupling enabled by flash irreversible generation of cationic and anionic species. Nat Commun 15, 4873 (2024).
DOI：10.1038/s41467-024-48723-1
